Popular Science on the Application of Polyester Carbon Black Viscosity-Reducing Dispersants

Popular Science on the Application of Polyester Carbon Black Viscosity-Reducing Dispersants

In coatings, inks, and plastics, polyester materials often require the addition of carbon black to achieve functions such as coloring and opacity. However, carbon black is prone to agglomeration, leading to increased system viscosity and affecting processing and product quality. The core function of polyester carbon black viscosity-reducing dispersants is to solve this problem. Their application needs to focus on scenario adaptation and key operations, as follows:

I. Main Application Scenarios and Core Requirements

1. Polyester Coatings

Commonly used in solvent-based, water-based, and solvent-free polyester coatings. Solvent-based coatings require dispersants that are compatible with both resin and solvent to avoid poor leveling during application; water-based coatings require dispersants with both hydrophilicity and adsorption capacity to prevent carbon black sedimentation; solvent-free coatings require dispersants with low volatility to avoid affecting coating adhesion. In this scenario, the dispersant can reduce coating viscosity to suit spraying and roller coating processes, and improve the uniformity of carbon black dispersion, ensuring consistent coating color and stable weather resistance.

2. Polyester Inks

Mainly used in polyester inks for packaging printing. These types of inks require high fluidity and drying speed. Carbon black agglomeration can easily lead to ink clogging and uneven printing. Dispersants can break up carbon black agglomerates, reduce ink viscosity to suit high-speed printing, and reduce floating color, ensuring rich colors and good adhesion in printed products.

3. Polyester Plastics Field

Used for coloring polyester-modified plastics (such as PET and PBT). Plastic processing requires high-temperature melting. Carbon black agglomeration not only causes uneven coloring but can also affect melt flow, leading to injection molding difficulties. Dispersants need to be heat-resistant, compatible with polyester resins, maintain stable carbon black dispersion during melting, reduce melt viscosity, and ensure uniform color and unaffected mechanical properties of plastic products.

II. Key Application Points

1. Adapting to System Characteristics

Select the dispersant according to the type of polyester system used in the application scenario: For solvent-based systems, choose a high molecular weight dispersant with good resin compatibility; for aqueous systems, choose anionic or polyether-modified hydrophilic dispersants; for solvent-free/high-temperature plastic systems, choose a low-volatility, heat-resistant dispersant. Simultaneously, considering the characteristics of carbon black, carbon black with a large specific surface area requires a dispersant with strong adsorption capacity, while carbon black with polar groups on its surface can preferentially use anionic dispersants.

2. Controlling Dosage and Process

The dosage is typically 1%-5% of the carbon black mass. Use the lower limit for low specific surface area carbon black and the upper limit for high specific surface area carbon black. Excessive dosage can easily lead to decreased system compatibility, while insufficient dosage will fail to break up agglomerates. In terms of process, the dispersant should first be mixed and dissolved with the polyester resin/solvent, then added to the carbon black in batches. After initial dispersion at high speed, it should be refined to 1-3μm using sand milling. The milling temperature should not exceed 60℃ to avoid dispersant failure.

3. Adapting to Environmental Parameters

Solvent-based systems require a mixed solvent with good resin solubility to avoid strong polar solvents damaging the dispersant structure; aqueous systems require adjusting the pH to 7.5-9.0 to enhance the adsorption effect of the dispersant; during plastic processing, the melting temperature needs to be controlled to ensure that the dispersant remains stable at high temperatures. The recommended solids content of the system is controlled between 30% and 45% to balance viscosity and product performance.

III. Summary 

The core of applying polyester carbon black viscosity reducers and dispersants is to solve the high viscosity problem caused by carbon black agglomeration through "suitable application scenarios + scientific operation," while simultaneously improving product processability and quality stability. Different polyester systems and carbon black properties exist in different application scenarios, requiring parameter optimization through small-scale trials. If special application challenges arise (such as high-solids coatings or high-temperature plastics), the solution can be further adjusted based on specific parameters.