Shoe coating defoamer: the"invisible guard"to eliminate bubbles

Shoe coating defoamer: the "invisible guard" to eliminate bubbles

In the field of shoe manufacturing, the quality of the coating directly affects the gloss, durability and overall aesthetics of the shoe surface. However, it is very easy to generate bubbles in the production, mixing, spraying and other links of the coating. If these bubbles are not eliminated in time, the coating will cause defects such as pinholes, shrinkage holes, and orange peel, and even reduce the protective performance of the coating. The emergence of shoe coating defoamers provides an efficient solution to this problem.

1. Where do bubbles come from? How does the defoamer "break the game"?

The bubbles in the coating mainly come from the following links:

Production stage: high-speed stirring during resin synthesis and pigment dispersion will involve air and form tiny bubbles;

Construction stage: the coating and air are mixed violently during spraying and brushing, or the rough surface of the substrate causes air to be trapped;

Storage stage: temperature changes or the escape of organic volatiles may cause delayed foaming.

If these bubbles are not eliminated in time, they will be "sealed" in the coating as the coating solidifies, forming defects. The mechanism of action of defoamers is aimed at this pain point:

Surface tension destruction: Defoamer molecules reduce the surface tension of the bubble membrane, causing it to become thinner and rupture locally;

Directional migration: Defoamer particles migrate to the bubble surface in the coating, destroying the bubble structure by "piercing" or "spreading";

Foam suppression persistence: Some defoamers can form a stable dispersion in the coating system and continuously inhibit the generation of new bubbles.

2. "Family members" of shoe coating defoamers

Based on the composition and action principle, shoe coating defoamers can be divided into three categories, each with its own unique advantages:

Mineral oil defoamers

Features: Mineral oil is used as the base, and dispersants such as hydrophobic silica are added, which has low cost and fast defoaming.

Advantages: Strong acid and alkali resistance, suitable for water-based and oily systems, especially stable in acidic or alkaline coatings.

Case: BASF WBA, Nopco NXZ and other models are often used in the pretreatment stage of polyurethane coatings for soles.

Silicone defoamers

Features: With polysiloxane as the core, it has extremely low surface tension and high defoaming efficiency.

Advantages:

Quick defoaming: Fluorine-modified silicone (such as BYK141) can spread on the bubble film instantly, achieving "break at the touch";

Long-lasting defoaming: Gas-silicon modified type (such as Hemmings 6800) pierces the bubble film through hydrophobic gas-phase silica to extend the defoaming time;

Wide compatibility: Silicone oil defoamers (such as Digo 810) are suitable for high shear environments to avoid demulsification during the grinding stage.

Polyether defoamers

Features: Based on polyether, directional defoaming is achieved by regulating the hydrophilic-hydrophobic balance.

Advantages: Good heat resistance, strong chemical stability, non-toxic and non-corrosive, suitable for environmentally friendly shoe coatings.

Case: Datian Chemical polyether-modified silicone defoamer, with an addition amount of only 0.001%, can significantly reduce costs while maintaining the leveling of the coating.

3. Four core advantages of defoamers for shoe coatings

Improve coating quality and create "flawless shoes"

Defoamers can eliminate defects such as pinholes and shrinkage caused by bubbles, making the coating smoother. For example, adding silicone defoamers to water-based acrylic coatings on the upper can increase the gloss of the coating by more than 20% and increase the scratch resistance by 15%.

By reducing the water absorption and permeability of the coating, defoamers can also improve the weather resistance and corrosion resistance of the coating and extend the service life of the shoe material.

Optimize the construction process to achieve "cost reduction and efficiency improvement"

Defoamers can reduce the viscosity of the coating, reduce the resistance during brushing or spraying, and make the construction smoother. For example, adding mineral oil defoamers to polyurethane coatings for soles can increase the spraying efficiency by 30% and reduce the rework rate.

Defoamers can also reduce paint waste by inhibiting bubble generation. According to statistics, the use of high-efficiency defoamers can increase the utilization rate of coatings by 10%-15%, directly reducing production costs.

Enhance coating performance and meet "multi-demand needs"

Defoamers can improve the physical and chemical properties of coatings. For example, adding polyether defoamers to UV-curing coatings for shoe materials can shorten the drying time by 20% while maintaining the hardness of the coating.

For functional shoe materials (such as antistatic and antibacterial coatings), defoamers can also prevent bubbles from interfering with the uniform distribution of additives and ensure stable performance.

Environmentally friendly and safe, helping "green manufacturing"

Modern defoamers mostly use non-toxic and non-corrosive formulas that comply with environmental standards such as ROHS and REACH. For example, defoamers specifically for water-based coatings (such as Yangzhou Lida LD-2044) are easy to disperse, have no residue, and will not pollute the environment.

Some defoamers can also reduce the ecological burden through biodegradation and promote the sustainable development of the shoe material industry.

4. How to choose a suitable defoamer?

Matching coating system: silicone or polyether defoamers are preferred for water-based coatings, and mineral oils can be used for oil-based coatings;

Taking into account both defoaming and compatibility: Through experimental screening, avoid excessive defoamers that cause shrinkage or turbidity in the coating;

Considering process requirements: shear-resistant silicone oil defoamers should be selected in high shear environments (such as grinding stages);

Evaluating cost-effectiveness: high-performance coatings can invest in high-end defoamers, and ordinary coatings can choose economical mineral oils.

Conclusion

From the colorful coating of sports shoes to the wear-resistant protection of safety shoes, shoe coating defoamers are guarding the quality and performance of every pair of shoes as "invisible guards". With the advancement of materials science, defoamers will develop in a more efficient, environmentally friendly and intelligent direction in the future, injecting more innovative vitality into shoe manufacturing.